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    Eszopiclone molecular structure

    Eszopiclone Stats & Data

    Eszop Lunesta
    NPS DataHub
    MW388.81
    FormulaC17H17ClN6O3
    CAS138729-47-2
    IUPAC[(7S)-6-(5-chloropyridin-2-yl)-5-oxo-7H-pyrrolo[3,4-b]pyrazin-7-yl] 4-methylpiperazine-1-carboxylate
    SMILESCN1CCN(CC1)C(=O)OC1c2nccnc2C(=O)N1c1ccc(Cl)cn1
    InChIKeyGBBSUAFBMRNDJC-INIZCTEOSA-N
    Psychoactive Class Depressant / Psychedelic

    Pharmacology

    DrugBank
    State Solid

    Description

    Eszopiclone, marketed by Sepracor under the brand-name Lunesta, is a nonbenzodiazepine hypnotic drug used to treat insomnia. It is the active stereoisomer of zopiclone, belonging to the class of drugs known as _cyclopyrrolones_. Cyclopyrrolone drugs demonstrate high efficacy and low toxicity, offering a safer alternative to other drugs used for insomnia. One major benefit of eszopiclone is that it is approved by the FDA for the long-term treatment of insomnia. This sets it apart from many other hypnotic sedatives, which are generally approved only for the relief of short-term (6-8 weeks) insomnia. Eszopiclone was initially approved by the FDA in 2004.

    Mechanism of Action

    The exact mechanism of action of eszopiclone is unknown at this time but is thought to occur via binding with the GABA receptor complexes at binding sites located near benzodiazepine receptors, possibly explaining its hypnotic and sedative effects. It has particular affinity for GABA-A (or GABAA) receptor subunits 1, 3 and 5. Eszopiclone increases GABA-A channel currents significantly. GABA-A channels are major inhibitory channels that cause CNS depression when their receptors are activated.

    Pharmacodynamics

    Eszopiclone rapidly induces sleep and decreases sleep latency. It also aids in the maintenance of sleep, preventing frequent awakenings. This drug has shown anticonvulsant and muscle relaxant properties in animals but is used in humans for its sedating effects. Eszopiclone is a central nervous system depressant with various effects. These include changes in alertness and motor coordination and the risk of next morning impairment, increasing with the amount of eszopiclone administered. Exercise caution and advise against driving a motor vehicle or activities that require full mental alertness the next morning. Complex sleep behaviors may result from eszopiclone use. Eszopiclone should be discontinued in these cases. Avoid the use of alcohol and other CNS depressants when eszopiclone is administered. Advise patients to skip the eszopiclone dose if alcohol has been consumed before bed or during the evening. Use the smallest dose of eszopiclone as possible, especially in elderly patients, who may experience exaggerated drug effects. Though the potential for dependence and abuse with eszopiclone is lower than for other hypnotic drugs, this drug has been abused and is known to cause dependence.

    Metabolism

    Following oral administration, eszopiclone is extensively biotransformed and the major metabolites are S-desmethylzopiclone and zopiclone-N-oxide, which are largely inactive.. The enzymes involved in the metabolism of eszopiclone are CYP3A (the primary metabolizing enzyme), CYP2C8, and CYP2E1. The N-oxide derivative shows weak pharmacological activity in animals. The N-desmethyl metabolite is pharmacologically active.

    Absorption

    Eszopiclone is rapidly absorbed and the peak concentration is reached within about 1 hour after oral administration. The mean AUC after a 3 mg dose of eszopiclone was 278 ng/mL × h. The consumption of a high-fat has been shown to slow absorption. Steady-state concentrations of eszopiclone are reached within 24-48 hours.

    Toxicity

    The oral LD50 of eszopiclone in rats is 980 mg/kg and 3200 mg/kg in rabbits. Symptoms of overdose may include mental status changes and somnolence, demonstrating general exaggeration of the drug's pharmacological effects. Perform gastric lavage and offer supportive treatment if an overdose is suspected, including intravenous fluids as required. Flumazenil may be used. Vital signs should be closely monitored in addition to patient symptoms. Appropriate medical interventions should be employed. The possibility of an overdose with multiple drugs should be considered. Ensure to contact the local poison control center for the most updated management of hypnotic drug overdose.

    Indication

    Eszopiclone is indicated for the treatment of insomnia.

    Half-life

    The half-life is 6.1 hours in healthy patients but is prolonged in various patients, including those with hepatic impairment, elderly patients, in addition to those taking CYP3A enzyme inhibiting drugs.

    Protein Binding

    This drug is 52-59% bound to plasma proteins.

    Elimination

    Only about 10% of an eszopiclone dose is found excreted in the urine as the parent drug. As much as 75% of an orally administered dose of racemic zopiclone as is found to be excreted in the urine in the form of metabolites. Eszopiclone, the S-isomer of racemic zopiclone, would likely show the same excretion pattern.

    Volume of Distribution

    The volume of distribution of eszopiclone is estimated at 89.9L

    Clearance

    The mean clearance of eszopiclone in young, healthy volunteers was 184 mL/min in one pharmacokinetic study.

    Receptor Profile

    Receptor Actions

    Modulators
    GABA-A receptor positive allosteric modulator (preferential affinity for alpha-1, alpha-3, and alpha-5 subunits)
    Other
    increases chloride channel opening frequency when GABA is present

    Receptor Binding

    Gamma-aminobutyric acid receptor subunit alpha-1 modulator
    Translocator protein agonist
    Gamma-aminobutyric acid receptor subunit alpha-2 modulator
    Gamma-aminobutyric acid receptor subunit alpha-3 modulator
    Gamma-aminobutyric acid receptor subunit alpha-5 modulator

    History & Culture

    2004–present

    Eszopiclone represents the isolated S-stereoisomer of zopiclone, a cyclopyrrolone sedative-hypnotic that had been available in Europe since 1989. The development of eszopiclone as a distinct pharmaceutical product was undertaken by Sepracor, who marketed the compound under the brand name Lunesta. The medication received approval from the United States Food and Drug Administration in December 2004 for the treatment of insomnia, entering the American market the following year. Eszopiclone belongs to a family of medications informally known as "Z-drugs," which also includes zopiclone, zaleplon, and zolpidem. These compounds were initially developed with the expectation that they would carry less potential for misuse compared to benzodiazepines; however, this assessment has been revised in subsequent years as cases of dependence and habituation have been documented. A notable distinction of eszopiclone compared to many other hypnotic medications is its approval for long-term treatment of insomnia, with evidence supporting efficacy for up to six months and some studies suggesting similar benefits after twelve months of use. By 2020, eszopiclone had become the 232nd most frequently prescribed medication in the United States, with over one million prescriptions dispensed annually.

    2007–2020

    In September 2007, Sepracor entered into a marketing agreement with GlaxoSmithKline to distribute eszopiclone in European markets under the brand name Lunivia. The following year, Sepracor submitted an authorization application to the European Medicines Agency and initially received a favorable assessment. However, the authorization effort encountered a significant obstacle in 2009 when the EMA determined that eszopiclone could not be granted "new active substance" status. The agency concluded that the compound was pharmacologically and therapeutically too similar to its parent compound zopiclone to warrant recognition as a distinct patentable product. Because zopiclone's patent had expired, this ruling would have enabled competing manufacturers to produce generic versions of eszopiclone for European markets. Sepracor subsequently withdrew its application. The arrangement with GlaxoSmithKline dissolved, and GSK instead pursued an agreement to market almorexant, an orexin receptor antagonist, though that compound's development was later discontinued due to adverse effects. Eszopiclone eventually became available in several European countries beginning in 2020, marketed by GL Pharma under the brand name Esogno.

    2009–present

    A 2009 article published in the New England Journal of Medicine titled "Lost in Transmission—FDA Drug Information That Never Reaches Clinicians" drew attention to concerns about the accessibility of clinical efficacy data for eszopiclone. The authors noted that prescribing information merely stated that eszopiclone was "superior to placebo" without providing specific efficacy metrics. The relevant clinical data was located on page 306 of a 403-page FDA medical review document. The article reported that in the largest phase 3 trial, participants receiving eszopiclone fell asleep an average of fifteen minutes faster and slept approximately thirty-seven minutes longer than those receiving placebo. Despite these improvements, patients in the treatment group still met diagnostic criteria for insomnia and did not report clinically meaningful enhancements in next-day alertness or functioning.

    Effect Profile

    Curated + 19 Reports
    Psychedelic 3.6

    Mild visuals and auditory effects with low headspace

    Visual Intensity×3
    4
    Headspace Depth×3
    1
    Auditory Effects×1
    4
    Body Load / Somatic Effects×1
    0

    Tolerance & Pharmacokinetics

    drugs.wiki

    Tolerance Decay

    Full tolerance 3d Half tolerance 8d Baseline ~14d

    Experience Report Analysis

    Erowid
    19 Reports
    2005–2021 Date Range
    7 With Age Data
    11 Effects Detected

    Demographics

    Gender Distribution

    Age Distribution

    Reports Over Time

    Effect Analysis

    Erowid

    Effects aggregated from 19 experience reports (19 Erowid)

    19 Reports
    11 Effects Detected
    6 Positive
    3 Adverse
    2 Neutral

    Effect Sentiment Distribution

    Confidence Distribution

    Positive Effects 6

    Sedation 42.1% 70%
    Stimulation 31.6% 70%
    Euphoria 26.3% 70%
    Music Enhancement 26.3% 70%
    Color Enhancement 21.1% 70%
    Empathy 15.8% 70%

    Adverse Effects 3

    Memory Suppression 26.3% 70%
    Motor Impairment 15.8% 70%
    Confusion 15.8% 70%

    Dosage Distribution

    Dose distribution from experience reports

    Median: 4.0 mg IQR: 3.0–6.0 mg n=12

    Real-World Dose Distribution

    62K Doses

    From 29 individual dose entries

    Oral (n=26)

    Median: 4.5mg 25th: 3.0mg 75th: 6.0mg 90th: 10.0mg
    mg/kg median: 0.057 mg/kg 75th: 0.086

    Form / Preparation

    Most common forms and preparations reported

    Body-Weight Dosing

    Dose relative to body weight from reports with weight data

    Median: 0.046 mg/kg IQR: 0.036–0.074 mg/kg n=11

    Redose Patterns

    Redosing behavior across 15 reports

    13.3% Redosed
    1.1 Avg Doses

    Legal Status

    Country Status Notes
    Canada Prescription medication Available as a prescription medication under the brand name Lunesta. Marketing authorization was granted in October 2020. Requires a prescription for lawful possession.
    United States Schedule IV Classified as a Schedule IV controlled substance under the Controlled Substances Act. Approved by the FDA on December 15, 2004 for the treatment of insomnia. The scheduling reflects recognized abuse potential comparable to benzodiazepines. Possession without a valid prescription may result in drug charges.
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