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    Naloxone molecular structure

    Naloxone Stats & Data

    NPS DataHub
    MW363.84
    FormulaC19H22ClNO4
    CAS357-08-4
    IUPAC(4R,4aS,7aR,12bS)-4a,9-dihydroxy-3-prop-2-enyl-2,4,5,6,7a,13-hexahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinoline-7-one hydrocloride
    SMILES[Cl-].C=CCN1CCC23C4C(=O)CCC3(O)C1Cc1ccc(O)c(O4)c12.[H+]
    InChIKeyRGPDIGOSVORSAK-XLHCXOCISA-N
    Chemical Class Opioid
    Psychoactive Class Depressant

    Pharmacology

    DrugBank
    State Solid Clearance The clearance of naloxone is 2500 L/day.

    Description

    Naloxone is an opioid antagonist medication used to block or reverse the effects of opioid drugs, particularly within the setting of drug overdoses which are rapidly becoming a leading cause of death worldwide. More specifically, naloxone has a high affinity for μ-opioid receptors, where it acts as an inverse agonist, causing the rapid removal of any other drugs bound to these receptors. When taken in large quantities, opioid medications such as morphine, hydromorphone, methadone, heroin, or fentanyl are capable of causing life-threatening symptoms such as respiratory depression, reduced heart rate, slurred speech, drowsiness, and constricted pupils. If untreated, this can progress to vomiting, absent pulse and breathing, loss of consciousness, and even death. Naloxone is indicated for the rapid reversal of these symptoms of central nervous system depression in opioid overdose. It's important to note that naloxone only works on opioid receptors within the body, and is therefore not capable of reversing the effects of non-opioid medications such as stimulants like methamphetamine or cocaine, or benzodiazepines like lorazepam or diazepam. Also known as the brand name product Narcan, naloxone is currently available by intramuscular (IM) or subcutaneous (SubQ) injection, nasal spray, or intravenous (IV) infusion.

    Mechanism of Action

    Naloxone is a competitive inhibitor of the µ-opioid receptor. Naloxone antagonizes the action of opioids, reversing their effects. If a patient has not taken opioids, naloxone does not have a significant effect on patients.

    Pharmacodynamics

    Naloxone is an opioid receptor antagonist indicated in the reversal of opioid overdoses. Naloxone has a shorter duration of action than opioids and multiple doses may be required. The therapeutic window of naloxone is wide, as it has no effect if a patient has not taken opioids. Patients treated with naloxone may experience opioid withdrawal and a person administering naloxone should be aware that reversal of opioid overdoses may not resolve all the symptoms a patient is experiencing if other drugs are involved.

    Metabolism

    Naloxone primarily undergoes glucuronidation to form naloxone-3-glucuronide. Naloxone is also N-dealkylated to noroxymorphone or undergoes 6-keto reduction to naloxol.

    Absorption

    An intranasal dose of naloxone is 42-47% bioavailable. An 8 mg dose of nasal naloxone reaches a Cmax of 12.3-12.8 ng/mL, with a Tmax of 0.25 hours, and an AUC of 16.7-19.0 h\*ng/mL. A 0.4 mg intramuscular dose reaches a Cmax of 0.876-0.910 ng/mL, with a Tmax of 0.25 hours, and an AUC of 1.94-1.95 h\*ng/mL. A 2 mg intravenous dose reaches a Cmax of 26.2 ng/mL with an AUC of 12.8 h\*ng/mL.

    Toxicity

    If a patient has not taken opioids, naloxone does not have a significant effect on patients. The oral LD50 in mice and rats is >1 g/kg. The intraperitoneal LD50 is 80 mg/kg in mice and 239 mg/kg in rats. The subcutaneous LD50 is 286 mg/kg in mice and 500 mg/kg in rats.

    Indication

    Naloxone nasal sprays are indicated for the emergency treatment of an opioid overdose or suspected opioid overdose. Intramuscular, intravenous, and subcutaneous injections are indicated for complete or partial reversal of opioid depression, diagnosis of known or suspected opioid overdose, and as an adjunct therapy in the treatment of septic shock. Sublingual tablets and films are formulated with buprenorphine for the treatment of opioid dependence. Naloxone is also formulated with pentazocine as an oral tablet for severe pain. Naloxone has been used off-label for the treatment of neuraxial opioid-induced pruritus.

    Half-life

    The mean half life of naloxone hydrochloride is 1.8-2.7 hours intranasally, 1.4 hours intramuscularly, and 1.2 hours intravenously. In neonates, the mean half life is 3.1 ± 0.5 hours.

    Protein Binding

    Naloxone is approximately 45% bound to albumin, but there is significant binding to other proteins.

    Elimination

    After oral or intravenous administration, naloxone is 25-40% eliminated in the urine within 6 hours, 50% in 24 hours, and 60-70% in 72 hours. The metabolites naloxone-3-glucuronide, noroxymorphone, and naloxol are all detected in the urine.

    Volume of Distribution

    The volume of distribution of naloxone is 200 L. Naloxone distributes into tissues rapidly. It can also cross the placenta and blood-brain barrier.

    Effect Profile

    Curated + 46 Reports
    Opioid 6.6

    Strong euphoria, itching/nausea, and sedation with mild pain relief

    Euphoria / Warmth×3
    105.0
    Analgesia×2
    4
    Sedation / Relaxation×1
    84.9
    Itching / Nausea×1
    104.4
    Catalog Erowid

    Tolerance & Pharmacokinetics

    drugs.wiki

    Tolerance Decay

    Full tolerance 1d Half tolerance 21d Baseline ~35d

    Experience Report Analysis

    Erowid
    46 Reports
    2000–2024 Date Range
    22 With Age Data
    16 Effects Detected

    Demographics

    Gender Distribution

    Age Distribution

    Reports Over Time

    Effect Analysis

    Erowid

    Effects aggregated from 46 experience reports (46 Erowid)

    46 Reports
    16 Effects Detected
    10 Positive
    5 Adverse
    1 Neutral

    Effect Sentiment Distribution

    Confidence Distribution

    Positive Effects 10

    Sedation 30.4% 70%
    Anxiety Suppression 30.4% 70%
    Euphoria 28.3% 70%
    Empathy 26.1% 70%
    Stimulation 26.1% 70%
    Tactile Enhancement 10.9% 70%
    Focus Enhancement 6.5% 70%
    Color Enhancement 6.5% 70%
    Music Enhancement 6.5% 70%
    Body High 6.5% 70%

    Adverse Effects 5

    Nausea 19.6% 70%
    Confusion 17.4% 70%
    Headache 17.4% 70%
    Increased Heart Rate 8.7% 70%
    Sweating 6.5% 70%

    Dose-Response Correlation

    How effect frequency changes across dose levels

    View data table
    Effect Common (n=13)
    Euphoria 61.5%
    Nausea 30.8%
    Empathy 30.8%
    Stimulation 30.8%
    Sedation 23.1%
    Anxiety Suppression 15.4%
    Dissociation 15.4%
    Music Enhancement 15.4%
    Tactile Enhancement 15.4%
    Sweating 15.4%

    Dose–Effect Mapping

    Experience Reports

    How reported effects shift across dose tiers, based on 46 experience reports.

    Limited tier coverage — most reports fall within the Common range. Effects at other dose levels may not be represented.

    Effect Common (n=13)
    euphoria
    62%
    nausea
    31%
    empathy
    31%
    stimulation
    31%
    sedation
    23%
    anxiety suppression
    15%
    dissociation
    15%
    music enhancement
    15%
    tactile enhancement
    15%
    sweating
    15%

    Dosage Distribution

    Dose distribution from experience reports

    Median: 2.0 mg IQR: 1.0–2.0 mg n=10

    Real-World Dose Distribution

    62K Doses

    From 102 individual dose entries

    Sublingual (n=64)

    Median: 2.0mg 25th: 0.69mg 75th: 2.0mg 90th: 3.0mg
    mg/kg median: 0.022 mg/kg 75th: 0.036

    Oral (n=10)

    Median: 4.0mg 25th: 1.25mg 75th: 8.0mg 90th: 8.8mg
    mg/kg median: 0.052 mg/kg 75th: 0.106

    Insufflated (n=7)

    Median: 0.5mg 25th: 0.38mg 75th: 1.0mg 90th: 1.4mg
    mg/kg median: 0.011 mg/kg 75th: 0.02

    Intravenous (n=7)

    Median: 2.0mg 25th: 1.5mg 75th: 3.0mg 90th: 4.0mg
    mg/kg median: 0.028 mg/kg 75th: 0.04

    Common Combinations

    Most co-occurring substances in experience reports

    Form / Preparation

    Most common forms and preparations reported

    Body-Weight Dosing

    Dose relative to body weight from reports with weight data

    Sublingual

    Median: 0.023 mg/kg IQR: 0.013–0.04 mg/kg n=10

    Unknown

    Median: 0.015 mg/kg IQR: 0.013–0.052 mg/kg n=5

    Redose Patterns

    Redosing behavior across 34 reports

    5.9% Redosed
    1.1 Avg Doses
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